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- ItemUV-based advanced oxidation process for nutrient stabilisation and organic micropollutant degradation in source-separated human urine(Department of Energy and Technology, Swedish University of Agricultural Sciences, 2023) Demissie, NatnaelUrine dehydration is one of the technological approach to recover nutrients in concentrated form from source separated urine. When drying fresh urine, nitrogen loss occurs due to hydrolysis of urea into ammonia unless methods to inactivate urease enzyme are employed. In addition, concerns arise when using urine-derived fertiliser due to the potential presence of organic micropollutants (pharmaceuticals). This thesis evaluated ultraviolet (UV) treatment as an alternative chemical-free nutrient stabilisation (urease inactivation) and organic micropollutant (OMP) degradation technology. Urease inactivation and OMP degradation in water and in urine (synthetic urine, real urine from human subjects) were studied in a photoreactor equipped with a low-pressure mercury UV lamp emitting light predominantly at 185 and 254 nm. Exposure of real urine to 80 min of UV irradiation resulted in more than 90% degradation of 18 out of 75 OMPs and 1-90% degradation of the remaining OMPs. Enzymatic activity fell below the detection limit for real urine exposed to 71 min of UV irradiation. However, electrical energy demand for reducing enzymatic activity below the detection limit in real fresh urine was 52-fold higher than for inactivation in synthetic fresh urine (without urea), while electrical energy demand was more than 10-fold higher for 90% OMP degradation in real fresh urine than in water. The inactivation and OMP degradation observed were probably due to direct photolysis and photo-oxidation. Presence of organic substances in real urine was the likely reason for less efficient inactivation of urease and OMP degradation, as such substances can competitively absorb incoming UV light and scavenge the free radicals formed during UV treatment. Although 20% urea was lost after UV treatment, there was no decrease in total nitrogen. In summary, UV treatment can stabilise urea-N and degrade OMPs in fresh urine and has potential for integration into urine diversion sanitation systems.
- ItemNeurocognitive modelling of human decision making(Department of Energy and Technology, Swedish University of Agricultural Sciences, 2019) Nazir, Azadeh HassannejadA central issue related to climate change and the path to a low carbon society is how we can change our attitudes and associated behavioral patterns. This type of decisions is concerned with how complex systems can be dealt with, conceptually, psychologically, as well as socially. In order to transform our society, we need to consider the relationship between brain, mind and behavior. One of the approaches to address this problem is to design computational models that can be used for simulations and scenario building. This thesis concerns the development and application of a neurocomputational model of the decision making process of an individual at experiential and social levels, considering both emotional and rational aspects. It is an attempt to bridge the gaps between micro (neuronal), meso (brain areas) and macro (cognition/behavior) levels with a focus on the mesoscale neurodynamics of cortical structures. The model is intended to link neural structures, functions, and includes effects of internal and environmental factors. The thesis is divided into two parts, corresponding to the two kinds of decision making: 1) experience-based and 2) social-based decision making. At an individual level, a final decision is the result of an integration of rational and emotional processes. The neural structures involved in cognition valuate the potential options regarding internal attitudes and rules, as well as external contexts. Decision values are based on neural properties of activity patterns associated with different actions. The option with the highest value is selected for in the decision making process. Human behavior is guided not only by subjective values and attitudes, but also by the perceived behavior of others. Learning from/about others through observation shapes our thoughts and behavioral patterns. The second part of the thesis deals with this social adaptive characteristic of an individual, where the dynamic changes of her behaviors are connected with trust. Traces of social influences on an individual’s decisions and social expectations (e.g. trust) have been observed in the rational and emotional brain structures and their functions. While the neurocomputational model is based on anatomical and physiological data of the modeled brain structures, no real world data have been available for model validation. Yet, simulation results mimic EEG and fMRI readouts, which could be compared with experimental/clinical data, when available. Future work intends to provide such data, but currently the modeling can only provide insights in the neurodynamic interactions between brain areas involved in decision making.
- ItemProcess efficiency in black soldier fly larvae composting of plant-based food industry waste(Department of Energy and Technology, Swedish University of Agricultural Sciences, 2021) Lindberg, LovisaBlack soldier fly larvae (BSFL) composting, in which biodegradable wastes are converted into animal-feed protein, is a technology that meets circular economy principles. The greatest potential BSFL composting is for mixed food waste, but only plant-based waste is permitted as feed for the larvae. It has lower biomass conversion efficiency (BCE), but this could be improved by pre-treatment.This thesis investigated process efficiency and GHG and ammonia emissions from BSFL composting using orange peel and broccoli and cauliflower, with ammonia or fungi pre-treatment. The impact of enzyme and ammonia pre-treatment time on process efficiency when using mixed lettuce and cabbage waste was also assessed. Following two weeks of substrate pre-treatment with ammonia and fungi, direct emissions of GHG and ammonia were evaluated. Lettuce and cabbage was pre-treated with enzymes or ammonia for 0-8 days prior to BSFL composting.BCE on a volatile solids (VS) basis was greater overall for food waste and lettuce and cabbage (~20%) than for orange peel and broccoli and cauliflower (~7%). The BCE was low (6%) in the orange peel control and even lower in both orange peel pre-treatments. Direct addition of enzymes at the start of BSFL composting gave 22% higher BCE compared with the control.Total emissions of N2O and CH4 were almost four-fold larger for the broccoli and cauliflower control than when pre-treated, indicating that ammonia pre-treatment significantly reduced total GHG emissions with no negative impact on BCE during BSFL composting, but with increased ammonia emissions.
- ItemFood waste in the food service sector - Quantities, risk factors and reduction strategies(Department of Energy and Technology, Swedish University of Agricultural Sciences, 2021) Malefors, ChristopherAn estimated one-third of all food produced is wasted, meaning that much of the negative environmental impact caused by food production is in vain. Global ambitions to reduce food waste include halving the levels by 2030, while the new EU food strategy views reducing food waste as a key issue in achieving a sustainable food system. This thesis presents detailed information on the volumes of food waste, where it occurs, why it occurs and what can be done to reduce it. The information originated from 1189 kitchens operating in establishments such as canteens, care homes, hotels, hospitals, preschools, schools and restaurants throughout Sweden, Norway, Finland and Germany. The results indicated that approximately 20% of food served in the catering sector is wasted, although there is large variation, with canteens reporting 50±9.4 g/portion of food waste and restaurants 190±30 g/portion. To identify risk factors and reasons for food waste, a more detailed subset of data on Swedish preschools and schools was analysed. Some of the risk factors identified related to kitchen infrastructure and guest age, which could be difficult or expensive to tackle as a first option. The main risk factor was the amount of food prepared relative to the number of guests attending, an issue that kitchens can tackle by forecasting. This thesis demonstrated the potential of forecasting attendance as a tool in planning catering operations. The current business-as-usual scenario, where food is prepared for all pupils enrolled, results in a mean error of 20-40%, whereas the best forecasting case, using neural network models, resulted in a mean error of 2-3%. However, forecasts can underestimate demand, creating shortages, so some margin must be added in practical use. Providing kitchens with information about roughly how many guests will attend a meal, plus a sufficient margin, and encouraging them to serve food from a backup stock in cases of forecast underestimation would overcome the problems of shortages, reduce food waste and contribute to a sustainable food system.
- ItemA New Approach in Profile Analysis with High-Dimensional Data Using Scores(Swedish University of Agricultural Sciences, Department of Energy and Technology, 2020) Cengiz, CigdemIn profile analysis, there exist three tests: test of parallelism, test of levels and test of flatness. In this thesis, these tests have been studied. Firstly, a classical setting, where the sample size is greater than the dimension of the parameter space, is considered. The hypotheses have been established and likelihood ratio tests have been derived. The distributions of these test statistics have been given. In the latter stage, all tests have been derived in a high-dimensional setting, where the number of parameters exceeds the number of sample size. Such settings have become more common due to the advances in computer technologies in the last decades. In high-dimensional data analysis, several issues arise with the dimensionality and different techniques have been developed to deal with these issues. We propose a dimension reduction method using scores that was first proposed by Läuter et al. (1996). To be able to find the specific distributions of the test statistics of profile analysis in this context, the properties of spherical distributions are utilized.